STUDENT SPACE · TOPIC 3

Aluminium extraction

Explain cryolite, electrode reactions and replacement of carbon anodes.

The essentials

Key vocabulary

EnglishChinese
bauxite铝土矿
cryolite冰晶石
anode阳极

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Why is an aqueous solution unsuitable for producing aluminium at the cathode?

Need a hint for Question 1?

Identify the ion charge before adding electrons. Balance atoms and charge separately.

Check Question 1

Hydrogen forms in preference to aluminium in an aqueous electrolyte. A molten electrolyte is used.

Question 2

Give the purpose of cryolite.

Need a hint for Question 2?

Consider the melting point of pure aluminium oxide.

Check Question 2

Cryolite lowers the operating temperature and therefore the energy required.

Question 3

Write the oxide-ion half-equation and explain why the anode needs replacing.

Need a hint for Question 3?

Oxide ions lose electrons; the resulting gas reacts with carbon.

Check Question 3

2O²⁻ → O₂ + 4e⁻. Oxygen reacts with the carbon anode, consuming it.

Use Lesson 3 in your worksheet for written practice. Your teacher will discuss those answers in class.

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